Fivefold scapular

 Blue scapular 

The Blessed Mother spoke to Ursula with these words: “Cease weeping, Ursula, and turn your sighs into heartfelt joy. Listen closely to what Jesus, whom I am holding in my lap, will say to you.”

Then Jesus revealed to Ursula that she would found a convent where 33 nuns, dressed in the same attire as the Most Blessed Virgin Mary of her vision, would live a life of solitude and seclusion. The Savior promised special graces and many spiritual gifts to those who would zealously follow this way of life.

The Venerable Servant of God besought the Lord to extend these favors also to such people who, living in the world, would have a special devotion to the mystery of the Immaculate Conception, observe chastity according to their station in life, and wear a small blue scapular. As a sign that her prayer had been heard, Jesus showed Ursula in a vision a multitude of angels distributing scapulars over the earth. This scene is artistically captured in a fresco at the Theatine Sisters’ Convent in Naples.

https://padrimariani.org/en/the-blue-scapular/

Red Scapular:

Sister Apolline reported that from 26 July 1846 to 14 September 1846 visions of Jesus and Mary appeared to her in the convent in Troyes, France and promised her that those who wear the scapular faithfully and contemplated the Passion of Jesus Christ would be granted a great increase of faith, hope and charity every Friday.[5]

She described the apparition of July 26, 1846:

Being in the chapel in the evening of the octave day of our Holy Father (St. Vincent de Paul), I saw, or thought I saw, Our Lord dressed in a flowing robe of a red color with a blue mantle hanging from his shoulders...He had in his hand a red scapular on which he was represented on the cross..."[6]

She further said that in a subsequent vision on September 14 (the Feast of the Exaltation of the Holy Cross) that Jesus told her that

The priests of the Mission alone are to give this scapular, and those who wear it when blessed by them will receive every Friday a full remission of their sins, and a great increase of faith, hope, and charity."[6]

https://en.m.wikipedia.org/wiki/Red_Scapular_of_the_Passion

Black scapular

The second black scapular is called "The Black Scapular of Our Lady of Dolors" or "The Black Scapular of the Seven Dolors of Mary." It is related to the Marian devotion of the Servites. Our Lady appeared to seven young Florentine noblemen, inviting them to follow Christ through the evangelical counsels. She gave them a black habit, telling them that "these garments shall be to you a perpetual memory of the sufferings of my heart." This is the beginning of the more common black scapular. The scapular witnesses a special dedication to Mary, and indicates her protection for the order. In turn, the members honor Mary in the Seven Dolors of her life:

https://udayton.edu/imri/mary/b/black-scapular.php

White scapular

white scapular with a red and blue cross. It is the badge of the confraternity of the Most Blessed Trinity, said to have originated in a vision given to Pope Innocent III in 1198, when an angel in this garb told him to approve the Trinitarian Order for the redemption of captives among the Moslems.

https://www.catholicculture.org/culture/library/dictionary/index.cfm?id=32197